PolyDADMAC Center

what is COD in watertreatment?

In water and wastewater treatment, COD (Chemical Oxygen Demand) is a critical water quality parameter that measures the amount of oxygen required to chemically oxidize organic and inorganic pollutants present in water.

What COD Tells Us in Water Treatment:

  • It indicates the total concentration of oxidizable contaminants (both biodegradable and non-biodegradable).

  • It helps assess the pollution strength of raw wastewater.

  • It is used to monitor treatment efficiency—a significant drop in COD from influent to effluent shows effective removal of pollutants.

  • It supports process control, regulatory compliance, and design of treatment systems.

How It’s Used Practically:

  1. Influent Monitoring: High COD in incoming wastewater may require pretreatment or process adjustments.

  2. Treatment Performance: Engineers compare COD levels before and after treatment (e.g., in primary clarifiers, biological reactors, or chemical coagulation units) to evaluate removal efficiency.

  3. Discharge Compliance: Environmental regulations often set maximum allowable COD levels in treated effluent to protect receiving waters.

  4. Industrial Wastewater Management: Industries (e.g., food processing, textiles, pharmaceuticals) use COD to track waste loads and optimize treatment.

Key Advantages Over BOD:

  • Faster results (2–3 hours vs. 5 days for BOD₅).

  • More comprehensive, as it oxidizes substances that microbes cannot break down.

  • Reproducible and reliable under lab conditions.

Limitations:

  • Does not distinguish between biodegradable and non-biodegradable matter.

  • Uses toxic chemicals (like chromium), requiring careful handling and disposal.

  • May overestimate actual oxygen demand in natural environments (since nature relies on biological processes).

Example in Practice:

  • A municipal wastewater plant might receive influent with COD = 500 mg/L and discharge effluent with COD = 30 mg/L, indicating >90% removal—meeting environmental standards.


In summary: In water treatment, COD is a fast, robust indicator of overall organic/inorganic pollution load, essential for designing, operating, and regulating treatment processes.